Ph meter is an electronic device used to
measure the concentration of hydrogen ions in the solution. Hydrogen ion concentration is
the value which decides the nature of any solution as acidic or alkaline. The
term pH was coined by danish scientist S.P.N Sorenson in 1909 . He has abbreviated pH
as " ponds hydro genii".
Fundamentally Ph Meter consists of a voltmeter attached to a ph-responsive
electrode and a reference ph electrode which is of fixed ph value. pH- responsive
electrode is generally made of glass while reference electrode is mercury-mercurous
chloride electrode, however a silver-silver chloride electrode is also used as
reference. As an ideal test condition we must ensure that only the pH value of
pH responsive electrode is changing upon concentration while the pH value of
reference electrode must be constant throughout the test process so as to generate
an effective potential difference.
When both these electrodes are immersed in a
solution they form a battery. Glass electrode generates a charge(potential
difference) which is directly according to the concentration of hydrogen ions,
means will be higher if the solution have rich hydrogen ion concentration. The
voltmeter attached measures the potential difference thus
generates due to glass electrode and reference electrode and the value thus
obtained is the pH score for the solution which we can compare to standard pH
chart and depending on where the pH score of solution lies, we say it acidic or
alkaline. As per the standard set for pH value in the field of chemistry and
biology, if the pH value is below 7 then the substance is called as of acidic
nature while if the pH score exceeds 7 it is said to have basic or alkaline
nature. More often if any solution have pH Controller value of exactly 7 then it is marked as neutral i.e. Neither
acidic nor alkaline.
For precise working of pH meter it must be
calibrated every time before use. If we are using pH meter in normal
use than daily calibration is required. The need of calibration required
because the glass electrode is not able to generate the same emf over a period
of time continuously. So in order to avoid any tolerances in the result,
calibration is a good practice. Depending upon the various factors each pH
meter is calibrated on number of iterations called as point, which is generally
termed as 1st point calibration, 2nd point calibration and 3rd point
calibration. Both the electrodes i.e. Glass electrode and reference electrode
have a definite set of maintenance instructions which must be followed each
time after completion of test and should be preserved carefully.
Types:
pH meter type ranges from simple and
inexpensive pen like meter to some more advanced laboratory installed pH Meter equipped with various input interfaces and display
indications. Some more advanced meters provides sensitivity towards temperature
when slight change in temperature can cause considerable variation in our
measurement.
Below are the set of precautions we must follow
to get most accurate measurement results:
·
Use
quality equipments
·
Maintenance
of electrodes
·
Proper
calibration of pH meter
·
Follow
proper test procedure
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